A smoldering shot of a barefoot, wild-haired Angelina Jolie in a wooden boat in Cambodia is the latest come-hither ad for Louis Vuitton. "People are not used to seeing Angelina in this situation," far from the red carpet, a Vuitton spokeswoman tells Women's Wear Daily. Jolie wears a Louis Vuitton bag slung over her shoulder and is wearing her own jungle-green clothes in the land of her adopted son, Maddox. The ad debuts in the International Herald Tribune tomorrow. Jolie is donating a portion of her pay —estimated to be millions of dollars—for Vuitton's "Core Values" ad campaign to charity. Click to see a full-size photo of the ad. (More Louis Vuitton stories.)